|
|
1,2-dihydroxy-5-(methylthio)pent-1-en-3-one + O2 <=> H+ + 3-(methylthio)propanoate + formate + CO
|
1.13.11.53
acireductone dioxygenase (Ni2+-requiring)
1.13.11.54
acireductone dioxygenase [iron(II)-requiring]
|
–
–
|
MK
|
| |
BRENDA:
BR48659
KEGG:
R07363
MetaCyc:
R146-RXN
|
|
|
|
3-(methylthio)propanoate + CoA + ATP <=> 3-methylthiopropionyl-CoA + AMP + diphosphate
|
6.2.1.44
3-(methylthio)propionyl---CoA ligase
|
–
|
MK
|
| |
BRENDA:
BR51149
KEGG:
R10820
MetaCyc:
RXN-12571
|
|
|
|
3-(methylthio)propanoate + 5-methyltetrahydrofolate + H+ <=> dimethylsulfoniopropionate + tetrahydrofolate
|
2.1.1.269
dimethylsulfoniopropionate demethylase
|
–
|
MK
|
| |
BRENDA:
BR49172
KEGG:
R10333
MetaCyc:
RXN-9736
|
|
|
|
3-(methylthio)propanoate + [Co(I)_methanethiol-specific_corrinoid_protein] + H+ <=> [methyl-Co(III)_methanethiol-specific_corrinoid_protein] + 3-Mercaptopropionate
|
2.1.1.251
methylated-thiol---coenzyme M methyltransferase
|
–
|
M
|
| |
MetaCyc:
RXN-8130
|
|
|
|
3-(methylthio)propanoate + tetrahydrofolate <=> 3-Mercaptopropionate + 5-methyltetrahydrofolate
|
2.1.1
|
–
|
M
|
| |
MetaCyc:
RXN-9738
|
|
|
|
1,2-dihydroxy-5-(methylthio)pent-1-en-3-one + O2 <=> 3-(methylthio)propanoate + formate
|
1.13.11.54
acireductone dioxygenase [iron(II)-requiring]
|
–
|
|
| |
BRENDA:
BS386946
|
|
|
|
L-2-hydroxy-4-methylthiobutanoic_acid + O2 <=> 3-(methylthio)propanoate + HCO3-
|
1.1.3.15
(S)-2-hydroxy-acid oxidase
|
–
|
|
| |
BRENDA:
BS257500
|
|
|
|
2-(dimethylsulfonio)propanoate + tetrahydrofolate <=> 3-(methylthio)propanoate + 5-methyltetrahydrofolate
|
2.1.1.269
dimethylsulfoniopropionate demethylase
|
–
|
|
| |
BRENDA:
BS453913
|
|
|
|
3-(methylthio)propanoate + coenzyme_M <=> methyl-CoM + 3-Mercaptopropionate
|
2.1.1.251
methylated-thiol---coenzyme M methyltransferase
|
–
|
|
| |
BRENDA:
BS418008
|
|
|
|
ATP + 3-(methylthio)propanoate + CoA <=> ADP + phosphate + 3-methylthiopropionyl-CoA
|
6.2.1.13
acetate---CoA ligase (ADP-forming)
6.2.1.B11
|
–
–
|
|
| |
BRENDA:
BS425945
|
|
|
|
a_[methyl-Co(III)_methanol-specific_corrinoid_protein] + 3-Mercaptopropionate <=> 3-(methylthio)propanoate + a_[Co(I)_methanol-specific_corrinoid_protein]
|
2.1.1.246
[methyl-Co(III) methanol-specific corrinoid protein]---coenzyme M methyltransferase
|
–
|
|
| |
BRENDA:
BS418345
|
|
|
|
a_[methyl-Co(III)_trimethylamine-specific_corrinoid_protein] + 3-Mercaptopropionate <=> 3-(methylthio)propanoate + a_[Co(I)_trimethylamine-specific_corrinoid_protein]
|
2.1.1.247
[methyl-Co(III) methylamine-specific corrinoid protein]---coenzyme M methyltransferase
|
–
|
|
| |
BRENDA:
BS419214
|
|
